1H- and 13C-n.m.r. assignments for structural elements of xylose-containing N-linked oligosaccharides, using 1D-and 2D-n.m.r. experiments.
1H-N.m.r. and 13C-n.m.r. spectral assignments for synthetic beta-D-Xyl-(1----2)-beta-D-Man-OMe, beta-D-Xyl-(1----2)-[alpha-D-Man-(1----3)]-beta-D-Man-OMe, beta-D-Xyl-(1----2)-[alpha-D-Man-(1----6)]-beta-D-Man-OMe, and beta-D-Xyl-(1----2)-[alpha-D-Man-(1----3)]-[alpha-D-Man-(1----6)]- beta-D-Man-OMe, which are structural elements of xylose-containing carbohydrate chains from N-glycoproteins, have been made on the basis of 1D and 2D (DQF 1H-1H COSY, HOHAHA) 500-MHz 1H-n.m.r. spectroscopy and 1D 50-MHz 13C-n.m.r. spectroscopy, respectively.
Bouwstra
J B
JB
Department of Bio-Organic Chemistry, Utrecht University, The Netherlands.
Kerékgyártó
J
J
Kamerling
J P
JP
Vliegenthart
J F
JF
D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D002247:Carbon Isotopes; D006859:Hydrogen; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008969:Molecular Sequence Data; D009844:Oligosaccharides; D014994:Xylose
D002247:Carbon Isotopes; D009844:Oligosaccharides; D006859:Hydrogen; D014994:Xylose