Isolation of 9-hydroxy-delta-tetradecalactone from lipid A of Pseudomonas diminuta and Pseudomonas vesicularis.
A lipid component was isolated from the fatty acid fraction of acid hydrolysates of lipid A derived from Pseudomonas diminuta JCM 2788 and Pseudomonas vesicularis JCM 1477 lipopolysaccharides. By structural analysis of the lipid and its trimethylsilyl and acetyl derivatives by thin-layer chromatography, gas chromatography-mass spectrometry, mass spectrometry, infrared spectrometry and 13C-NMR, it was identified as 9-hydroxy-delta-tetradecalactone.
Arata
S
S
Department of Microbial Chemistry, School of Pharmaceutical Sciences, Showa University, Tokyo, Japan.
Hirayama
T
T
Kasai
N
N
Itoh
T
T
Ohsawa
A
A
D007783:Lactones / Q000302:isolation & purification*; D008050:Lipid A / Q000032:analysis*; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D015394:Molecular Structure; D011549:Pseudomonas / Q000032:analysis*
D007783:Lactones; D008050:Lipid A; C061081:9-hydroxy-gamma-tetradecalactone