Minor and trace sterols in marine invertebrates. 61. Isolation and structure elucidation of new A-nor sterols from the marine sponge Phakellia aruensis.
An examination of the Australian sponge Phakellia aruensis led to the isolation and identification of sterols with six different nuclei. Eight new sterols were isolated which included three delta 15-A-nor sterols, three delta 7-A-nor sterols, and two saturated A-nor sterols. Their structures were established through mass spectrometry and 1H-NMR spectral studies.
Malik
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Department of Chemistry, Stanford University, CA 94305.
Djerassi
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C
D000818:Animals; D055598:Chemical Phenomena; D002621:Chemistry; D002775:Cholestadienols / Q000302:isolation & purification; D002777:Cholestanols / Q000302:isolation & purification; D004875:Ergosterol / Q000031:analogs & derivatives / Q000302:isolation & purification; D009682:Magnetic Resonance Spectroscopy; D009654:Norsteroids / Q000302:isolation & purification*; D011161:Porifera / Q000032:analysis; D013261:Sterols / Q000302:isolation & purification*
D002775:Cholestadienols; D002777:Cholestanols; D009654:Norsteroids; D013261:Sterols; D004875:Ergosterol