title: Technetium carboxylate complexes--III. A new synthetic route to hexakis-(isonitrile) technetium(I) salts.
abstract: Hexakis(isonitrile)technetium(I) cations have been prepared from carboxylate based technetium starting materials. The following ligands have been employed: t-butyl, n-butyl, cyclohexyl, and benzyl isonitrile. The products have been characterized by u.v.-visible and i.r. spectroscopy, cyclic voltammetry, fast atom bombardment mass spectrometry and electrophoresis.
authors.affiliation: Department of Chemistry, Purdue University, West Lafayette, IN 47907.
authors.forename: C M
authors.initials: CM
authors.lastname: Kennedy
authors.forename: T C
authors.initials: TC
authors.lastname: Pinkerton
mesh_terms: D009570:Nitriles; D009942:Organometallic Compounds / Q000138:chemical synthesis*; D013667:Technetium
chemical_list: D009570:Nitriles; D009942:Organometallic Compounds; D013667:Technetium