title: [Initiation of nonenzymatic lipid peroxidation in a Fe2+-ascorbate-linolenate system].
abstract: Using spin trapping method there were discovered and identified the radicals of linolenic acid formed when initiating its peroxidation by the system Fe2+-ascorbate. Mechanism of formation of linolenic acid radicals and their role in initiation of peroxidation were studied. A scheme of reactions of peroxidation initiation in the system Fe2+-ascorbate. linolenic acid is proposed.
authors.forename: O A
authors.initials: OA
authors.lastname: Azizova
authors.forename: A N
authors.initials: AN
authors.lastname: Osipov
authors.forename: V M
authors.initials: VM
authors.lastname: Savov
authors.forename: A V
authors.initials: AV
authors.lastname: Iakh''iaev
authors.forename: V E
authors.initials: VE
authors.lastname: Zubarev
mesh_terms: D001205:Ascorbic Acid / Q000378:metabolism*; D004578:Electron Spin Resonance Spectroscopy; D005296:Ferrous Compounds / Q000378:metabolism*; D005609:Free Radicals; D066298:In Vitro Techniques; D007501:Iron / Q000378:metabolism*; D007700:Kinetics; D008042:Linolenic Acids / Q000378:metabolism*; D008054:Lipid Peroxides / Q000378:metabolism*; D010084:Oxidation-Reduction; D017962:alpha-Linolenic Acid
chemical_list: D005296:Ferrous Compounds; D005609:Free Radicals; D008042:Linolenic Acids; D008054:Lipid Peroxides; D017962:alpha-Linolenic Acid; D007501:Iron; D001205:Ascorbic Acid
vernacular_title: Initsiirovanie nefermentativnogo perekisnogo okisleniialipidov v sisteme Fe2+-askorbat-linolenat.