Interfacial tensions and partition coefficients in water/heptane systems containing 2,6-diisopropylphenol, n-alkylphenols and cycloalkanols.
The free energies of absorption, dehydration, and transfer in a heptane-water system for a set of phenolic compounds and a series of cycloalkanols have been investigated. The free energy of adsorption depends only upon the molecular surface area of the hydrophobic fraction of the molecule, whereas the free energy of dehydration is independent of this fraction.
D055598:Chemical Phenomena; D002627:Chemistry, Physical; D006536:Heptanes; D010636:Phenols / Q000032:analysis*; D015742:Propofol; D012995:Solubility; D013500:Surface Tension; D014867:Water
D006536:Heptanes; D010636:Phenols; D014867:Water; D015742:Propofol