Laser desorption Fourier transform mass spectra of malto-oligosaccharides.
Laser desorption mass spectra of malto-oligomers, including starch, have been obtained using Fourier transform mass spectrometry. Fragmentations of these oligomers have been examined after doping with metal salts to obtain cation-attachment ions. Doping starch with NaCl, KBr and Ag2O results in analogous cation-attachment oligosaccharide fragment ions for all three metal ions. A distinct and unusual fragmentation pattern is observed for the larger oligomers.
Coates
M L
ML
Wilkins
C L
CL
D005583:Fourier Analysis; D007834:Lasers; D013058:Mass Spectrometry / Q000379:methods; D009844:Oligosaccharides / Q000032:analysis*; D013329:Structure-Activity Relationship
D009844:Oligosaccharides; C021705:maltooligosaccharides