Semiquinone anion radicals of catechol(amine)s, catechol estrogens, and their metal ion complexes.
The characterization and identification of semiquinone radicals from catechol(amine)s and catechol estrogens by electron spin resonance spectroscopy is addressed. The use of diamagnetic metal ions, especially Mg2+ and Zn2+ ions, to detect transient semiquinone radicals in biological systems and to monitor their reactions, is discussed. A brief account of the identification and reactions of quinones is also presented.
D000818:Animals; D016227:Benzoquinones; D002395:Catecholamines; D002396:Catechols; D055598:Chemical Phenomena; D002621:Chemistry; D004578:Electron Spin Resonance Spectroscopy; D002393:Estrogens, Catechol; D005609:Free Radicals; D007700:Kinetics; D008670:Metals; D010084:Oxidation-Reduction; D010088:Oxidoreductases / Q000378:metabolism; D010777:Photochemistry; D011809:Quinones / Q000633:toxicity; D013329:Structure-Activity Relationship
D016227:Benzoquinones; D002395:Catecholamines; D002396:Catechols; D002393:Estrogens, Catechol; D005609:Free Radicals; D008670:Metals; D011809:Quinones; C025232:semiquinone radicals; D010088:Oxidoreductases