[Study of molecular mobility in biological membranes by 2-mm band ESR spectroscopy].
Temperature relationship was measured of ESR spectra of spin probes--derivatives of fatty acids whose nitroxyl fragments are incorporated into surface and inner layers of phosphatidylcholine liposomes (T = 180-260 K), as well as of the probe in model ethanol solution (T = 110-220 K). Data on the nature and rotation frequency of probe nitroxyl fragments were obtained from the analysis of the spectra. It was shown that the frequency of the probes movement in the systems under study corresponds to the slow movement region, i.e. it is not above 10(7) s-1.
D004578:Electron Spin Resonance Spectroscopy; D005227:Fatty Acids; D005609:Free Radicals; D008081:Liposomes; D013113:Spin Labels
D005227:Fatty Acids; D005609:Free Radicals; D008081:Liposomes; D013113:Spin Labels
Issledovanie molekuliarnoĭ podvizhnosti v biologicheskikh membranakh metodom spektroskopii EPR 2-mm diapazona.