title: Complete 1H-NMR spectral assignments for globotriaosyl-Z- and isoglobotriaosyl-E-ceramide.
abstract: Two-dimensional scalar-correlated (COSY) 1H-NMR spectra of the title compounds, and phase-sensitive COSY spectrum of lactosylceramide, have been fully assigned and some spectral reassignments for related structures suggested. Glycosylation-induced shifts, and shielding by Z- and E-ceramide residues are discussed.
authors.affiliation: Max-Planck-Institut für Medizinische Forschung, Heidelberg, F.R.G.
authors.forename: J
authors.initials: J
authors.lastname: Dabrowski
authors.forename: K
authors.initials: K
authors.lastname: Trauner
authors.forename: K
authors.initials: K
authors.lastname: Koike
authors.forename: T
authors.initials: T
authors.lastname: Ogawa
mesh_terms: D005915:Globosides / Q000032:analysis*; D006028:Glycosphingolipids / Q000032:analysis*; D009682:Magnetic Resonance Spectroscopy; D014281:Trihexosylceramides
chemical_list: D005915:Globosides; D006028:Glycosphingolipids; D014281:Trihexosylceramides; C018549:globotriaosylceramide; C037097:isoglobotriaosylceramide