SH vibrational frequency and hydrogen bond in biological thiols: a critical analysis.
Applications of vibrational spectroscopy to the study of thiol group in biomolecules are critically presented. Correlations between SH frequencies and thiol environment are discussed and problems related to the actual occurrence of H-bonds are particularly analyzed.
Rosei
M A
MA
Dipartimento di Scienze Biochimiche, Università La Sapienza, Roma, Italia.
D006860:Hydrogen Bonding; D013438:Sulfhydryl Compounds; D014732:Vibration
D013438:Sulfhydryl Compounds