Gas chromatographic-mass spectrometric determination of epoxidized soybean oil contamination of foods by migration from plastic packaging.
A method for the quantitative determination of epoxidized soybean oil (ESBO) in foods is described. The procedure involves addition of a diepoxidized fatty acid ester internal standard, followed by lipid extraction from the food and transmethylation under basic conditions. Without further cleanup, the methylated fatty acid epoxides are derivatized to form 1,3-dioxolanes, which are then determined by capillary gas chromatography-mass spectrometry with selected ion monitoring. A detection limit of 2.0 mg/kg of epoxidized soybean oil in foods and a relative standard deviation of 7% have been achieved routinely. The method has been applied successfully to the analysis of cheeses, sandwiches, cakes, and microwave-cooked meals which have been contaminated with ESBO by migration from PVC film.
Castle
L
L
Ministry of Agriculture, Fisheries and Food, Norwich, United Kingdom.
Sharman
M
M
Gilbert
J
J
D004852:Epoxy Compounds / Q000032:analysis; D005504:Food Analysis; D005506:Food Contamination / Q000032:analysis*; D005511:Food Handling; D008401:Gas Chromatography-Mass Spectrometry; D007202:Indicators and Reagents; D010938:Plant Oils / Q000032:analysis*; D010969:Plastics / Q000032:analysis; D013024:Soybean Oil / Q000032:analysis*
D004852:Epoxy Compounds; D007202:Indicators and Reagents; D010938:Plant Oils; D010969:Plastics; D013024:Soybean Oil