(Z,Z)-1,1'-(1,6-hexanediyl)bis(2-phenyldiazene) 2,2'-dioxide: a bis(azoxy) compound.
C18H22N4O2, Mr = 326.40, orthorhombic, Pbca, a = 19.475 (10), b = 10.435 (20), c = 8.762 (20) A, V = 1780.6 A3, Z = 4, Dx = 1.22 g cm-3, lambda(Mo K alpha) = 0.7107 A, mu = 0.76 cm-1, F(000) = 696, room temperature, 1564 reflections averaged from two octants, R = 0.044, wR = 0.050 for 669 observed reflections with I greater than sigma(I). The molecule has inversion symmetry and is nearly planar. The azoxy group is trans-substituted. Molecular packing is in herringbone-type layers.
Williams
D E
DE
Department of Chemistry, University of Louisville, KY 40292.
Bundoc
A
A
Taylor
K G
KG
D001391:Azo Compounds; D003979:Diazonium Compounds; D015394:Molecular Structure; D013237:Stereoisomerism; D014961:X-Ray Diffraction
D001391:Azo Compounds; D003979:Diazonium Compounds; C062750:1,1'-(1,6-hexanediyl)bis(2-phenyldiazene)-2,2'-dioxide