Magnesium interactions with lithium and sodium salts of adenosine triphosphate: an investigation by phosphorus-31 nuclear magnetic resonance spectroscopy.
Phosphorus NMR spectra were recorded for complexes of Na2ATP and Li4ATP with varying concentrations of magnesium, calcium and lithium. Each ion caused a shift in the phosphorus resonances, usually downfield, and a decrease in the 31P-31P coupling constant. The sodium ATP formed a 1:1 complex with each ion and a 1:2, ATP:Mg complex with magnesium whilst lithium ATP gave evidence to suggest the formation of bis(nucleotide) complexes.
Hughes
M S
MS
Biomedical Research Laboratory, Centre for Health Sciences, Wolverhampton, UK.
Partridge
S
S
Marr
G
G
Birch
N J
NJ
D000255:Adenosine Triphosphate; D002118:Calcium; D007700:Kinetics; D008094:Lithium; D008274:Magnesium; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D010758:Phosphorus; D012964:Sodium
D010758:Phosphorus; D000255:Adenosine Triphosphate; D008094:Lithium; D012964:Sodium; D008274:Magnesium; D002118:Calcium