Structure of bis(methanol)(meso-tetraphenylporphinato)manganese(III) hexachloroantimonate bis(tetrachloroethane) solvate.
[Mn(C44H30N4)(CH3OH)2] [SbCl6].2C2H2Cl4, Mr = 1401.93, triclinic, P1, a = 11.104 (3), b = 12.086 (6), c = 12.619 (4) A, alpha = 115.33 (3), beta = 104.75 (2), gamma = 91.75 (3) degrees, V = 1461.3 A3, Z = 1, Dm = 1.58, D chi = 1.59 Mg m-3, lambda(Mo K alpha) = 0.71073 A, mu = 1.359 mm-1, F(000) = 698, T = 293 K, R = 0.079 for 4822 unique observed reflections. The manganese ion is coordinated to two methanol oxygens, Mn--O = 2.283 (5) A, and four porphinato nitrogen atoms, average Mn--N = 2.002 (5) A.
Scheidt
W R
WR
Department of Chemistry, University of Notre Dame, Indiana 46556.
Pearson
W B
WB
Gosal
N
N
D008958:Models, Molecular; D008968:Molecular Conformation; D013461:Sulfur Oxides; D014961:X-Ray Diffraction / Q000379:methods
D013461:Sulfur Oxides; C023589:thionyl chloride; C062539:thionyl bromide