Studies on some iridium(III) complexes with Schiff bases derived from amino carboxylic acids.
The reactions of iridium(III) chloride with different Schiff bases gave complexes of types [Ir(SB)3], [Ir(SB')Cl(H2O)2], [Ir(SB'')Cl2]n, [Ir(SB'' ')Cl(H2O)]n (SBH = Schiff bases derived from anthranilic acid and benzaldehyde, acetophenone, vanillin, cinnamaldehyde or m-hydroxyacetophenone; SB'H2 = Schiff bases derived from anthranilic acid and salicylaldehyde or o-hydroxyacetophenone; SB''H = Schiff bases derived from p-aminobenzoic acid and benzaldehyde, acetophenone, vanillin, cinnamaldehyde, or m-hydroxyacetophenone; SB'' 'H2 = Schiff bases derived from p-aminobenzoic acid and salicylaldehyde or o-hydroxyacetophenone). These complexes have been characterized on the basis of elemental analyses, conductance, magnetic moment, and spectral (electronic, i.r., and 1H n.m.r.) data. The electronic spectra reveals octahedral geometry for these complexes except for [Ir(SB'')Cl2]n, which is trigonal bipyramidal. The thermal behavior of these complexes has also been studied by TG, DTG, and DSC techniques. The different kinetic parameters, viz., order of reaction, activation of energy, and heat of reaction were calculated. The antifungal and antiviral activities of the complexes with Schiff bases derived from anthranilic acid have also been investigated.
Sharma
V K
VK
Department of Chemistry, University of Gorakhpur, India.
Pandey
O P
OP
Sengupta
S K
SK
D010129:4-Aminobenzoic Acid; D062365:Aminobenzoates; D000935:Antifungal Agents; D000998:Antiviral Agents; D004553:Electric Conductivity; D004735:Energy Transfer; D006358:Hot Temperature; D007495:Iridium; D009682:Magnetic Resonance Spectroscopy; D008826:Microbial Sensitivity Tests; D012545:Schiff Bases / Q000032:analysis / Q000138:chemical synthesis* / Q000494:pharmacology; D062367:ortho-Aminobenzoates
D062365:Aminobenzoates; D000935:Antifungal Agents; D000998:Antiviral Agents; D012545:Schiff Bases; D062367:ortho-Aminobenzoates; C031385:anthranilic acid; D007495:Iridium; D010129:4-Aminobenzoic Acid