[Synthesis and properties of C13-substituted retinals].
Several analogues of all-trans-retinal were synthesised, containing, instead of CH3-group at C13, the following substituents: H, C[2H]3, C2H5, iso-C3H7, C4H9, C6H5 or alpha-C10H8. The compounds synthesised on coupling with bacterioopsin gave artificial chromoproteins, which retained the ability to participate in the cycle of photochemical transformations and H+-transport.
Eremin
S V
SV
Mitsner
B I
BI
Danshina
S V
SV
Khitrina
L V
LV
D001436:Bacteriorhodopsins / Q000032:analysis; D055598:Chemical Phenomena; D002621:Chemistry; D012172:Retinaldehyde / Q000031:analogs & derivatives / Q000032:analysis / Q000138:chemical synthesis*; D012176:Retinoids / Q000138:chemical synthesis*
D012176:Retinoids; D001436:Bacteriorhodopsins; D012172:Retinaldehyde
Sintez i svoĭstva C13-zameshchennykh retinaleĭ.