[Structure of the reaction adduct of xanthothricin with acetone].
Reaction of xanthothricin demethylation by amines in acetone as a solvent yielded a new compound with a formula of C10H13N5O3. Mass spectrometry, 1H NMR-spectroscopy and x-ray analysis showed that the compound was 4H-1,6-dimethyl-4a(2-oxopropyl)-pyrimido-[5,4-e]-1 ,2,4-triazine-5,7-dione.
Dovzhenko
S A
SA
Esipov
S E
SE
Aleksandrov
G G
GG
Kliuev
N A
NA
Chernyshev
A I
AI
D000096:Acetone / Q000494:pharmacology*; D002855:Chromatography, Thin Layer; D004347:Drug Interactions; D009682:Magnetic Resonance Spectroscopy; D013058:Mass Spectrometry; D008745:Methylation; D011744:Pyrimidinones / Q000494:pharmacology; D014227:Triazines / Q000032:analysis* / Q000302:isolation & purification / Q000494:pharmacology; D014961:X-Ray Diffraction
C056054:4H-1,6-dimethyl-4a(2-oxopropyl)pyrimido-(5,4e)-1,2,4-triazine-5,7-dione; D011744:Pyrimidinones; D014227:Triazines; D000096:Acetone; C009570:toxoflavin
Stroenie addukta reaktsii ksantotritsina s atsetonom.