Absolute and relative configuration of erythroskyrin.
We have reisolated erythroskyrin from Penicillium islandicum and have determined the relative stereochemistry of the compound through extensive 1H- and 13C-nmr studies. The absolute stereochemistry was determined by nmr studies of the O-methylmandelate esters.
Beutler
J A
JA
Program Resources, Inc., National Cancer Institute-Frederick Cancer Research Facility, Maryland.
Hilton
B D
BD
Clark
P
P
Tempesta
M S
MS
Corley
D G
DG
D055598:Chemical Phenomena; D002621:Chemistry; D002942:Circular Dichroism; D004951:Esterification; D009682:Magnetic Resonance Spectroscopy; D009183:Mycotoxins / Q000302:isolation & purification; D010407:Penicillium / Q000032:analysis; D011090:Polyenes / Q000302:isolation & purification; D013237:Stereoisomerism
D009183:Mycotoxins; D011090:Polyenes; C012959:erythroskyrine