[Spectrum properties of steroid hormones, sapogenins and alkaloids in the Chugaev reaction: effect of the structure].
Spectral characteristics of the products of the Chugaev reaction with steroid hormones, sapogenins and alkaloids are analyzed by spectrophotometry and fluorescent spectroscopy. They are established to be dependent on a degree of nonsaturation, position of double bonds, nature and position of substitutes in the molecule structure. The reaction is shown possible to be used for quantitative determination of a number of steroids. The fluorescent spectroscopy application essentially increases sensitivity of the method.
Kholodova
Iu D
IuD
D000470:Alkaloids / Q000032:analysis*; D055598:Chemical Phenomena; D002621:Chemistry; D012502:Sapogenins / Q000032:analysis*; D013050:Spectrometry, Fluorescence; D013256:Steroids / Q000032:analysis*; D013329:Structure-Activity Relationship
D000470:Alkaloids; D012502:Sapogenins; D013256:Steroids
Spektral'nye svoĭstva steroidnykh gormonov, sapogeninov i alkaloidov v reaktsii Chugaeva; zavisimost' ot struktury.