Unexpected formation of the 3,6-anhydro and 6-O-methyl-1-fluoro derivatives of galabiose on attempted substitution of HO-6 by fluorine in methyl 4-O-alpha-D-galactopyranosyl-beta-D-galactopyranoside (methyl beta-D-galabioside).
Chemical Center, Lund Institute of Technology, Sweden.
J
J
Kihlberg
T
T
Frejd
K
K
Jansson
G
G
Magnusson
D002236:Carbohydrate Conformation; D004187:Disaccharides / Q000138:chemical synthesis*; D005459:Fluorides; D005690:Galactose; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy / Q000379:methods; D008756:Methylgalactosides / Q000138:chemical synthesis*; D008759:Methylglycosides / Q000138:chemical synthesis*
D004187:Disaccharides; D007202:Indicators and Reagents; D008756:Methylgalactosides; D008759:Methylglycosides; D005459:Fluorides; D005690:Galactose