A novel synthesis of carbocyclic C-nucleoside precursors by nonoxidative C-C bond fission.
New carbocyclic c-nucleoside precursors have been synthesized in stereocontrolled manner by nonoxidative C-C bond fission (i.e., Grob fragmentation or retrograde aldol reaction) starting from Diels-Alder adducts of cyclopentadiene with 3-acetoxyacrylates or dimethyl 2-acetoxymethylenemalonate.
D002264:Carboxylic Acids; D055598:Chemical Phenomena; D002621:Chemistry; D007202:Indicators and Reagents; D009705:Nucleosides / Q000138:chemical synthesis*
D002264:Carboxylic Acids; D007202:Indicators and Reagents; D009705:Nucleosides