Determination of trialkyllead species in water samples.
An analytical compound procedure is described for the determination of trimethyl- and triethyllead in water samples like rain, melted snow, and surface waters. The method consists of an enrichment step (adsorption onto and elution from silica gel), a chromatographic separation with column switching (HPLC including pre-column enrichment), and a spectrophotometric detection (chemical reaction detector). The detection limits for the whole procedure, starting with 500 ml sample volume, are 15 pg/ml and 20 pg/ml for trimethyl- and triethyllead resp. The standard deviation for repeated analysis of a sample containing 90 pg Et3Pb+/ml is calculated to +/- 4%. The method also covers the analysis of the chemically mixed trialkyllead species Me2EtPb+ and MeEt2Pb+. The investigation of several water samples taken from different locations shows the presence of trimethyl- and triethyllead in the concentration range of 20-100 pg/ml.
D005618:Fresh Water / Q000032:analysis*; D009942:Organometallic Compounds / Q000032:analysis*; D011891:Rain; D014867:Water / Q000032:analysis*; D014873:Water Pollutants / Q000032:analysis*; D014874:Water Pollutants, Chemical / Q000032:analysis*
D009942:Organometallic Compounds; D014873:Water Pollutants; D014874:Water Pollutants, Chemical; D014867:Water