Separation of the enantiomers of fluazifop and other 2-phenoxypropionic acids using chiral metal chelate additives in reversed-phase high-performance liquid chromatography.
Most of the work on the use of chiral ligand-exchange systems in reversed-phase liquid chromatography has been focussed on the resolution of the enantiomers of amino acids. This paper describes the novel use of L-prolyl-n-octylamide-Ni(II) in the mobile phase for the resolution of the enantiomers of fluazifop and other phenoxypropionic acids.
D002614:Chelating Agents; D002851:Chromatography, High Pressure Liquid; D003300:Copper; D004095:Dihydropyridines; D006540:Herbicides / Q000302:isolation & purification*; D006863:Hydrogen-Ion Concentration; D007202:Indicators and Reagents; D011422:Propionates / Q000302:isolation & purification*; D011725:Pyridines / Q000302:isolation & purification*; D013056:Spectrophotometry, Ultraviolet; D013237:Stereoisomerism; D015032:Zinc
D002614:Chelating Agents; D004095:Dihydropyridines; D006540:Herbicides; D007202:Indicators and Reagents; D011422:Propionates; D011725:Pyridines; D003300:Copper; C050582:fluazifop; D015032:Zinc