[Synthesis of capsular polysaccharide of Streptococcus pneumoniae type 14. 4. Polycondensation of the monomer and characteristics of the polysaccharide].
Synthesis of a regular branched polysaccharide [6(Gal beta 1-4)GlcNAc beta 1-3Gal beta 1-4Glc beta 1]n whose structure corresponds to that of the capsular polysaccharide of Streptococcus pneumoniae type 14, is described, involving a stereospecific polycondensation of the tetrasaccharide monomer, deacylation, and N-acetylation.
Nifant'ev
N E
NE
Bakinovskiĭ
L V
LV
Kochetkov
N K
NK
D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D002473:Cell Wall / Q000276:immunology; D055598:Chemical Phenomena; D002621:Chemistry; D009682:Magnetic Resonance Spectroscopy; D011135:Polysaccharides, Bacterial / Q000032:analysis / Q000138:chemical synthesis*; D013296:Streptococcus pneumoniae / Q000276:immunology*
D011135:Polysaccharides, Bacterial
Sintez kapsuliarnogo polisakharida Streptococcus pneumoniae, tip 14. 4. Polikondensatsiia monomera i kharakteristika polisakharida.