title: [Synthesis of capsular polysaccharide of Streptococcus pneumoniae type 14. 4. Polycondensation of the monomer and characteristics of the polysaccharide].
abstract: Synthesis of a regular branched polysaccharide [6(Gal beta 1-4)GlcNAc beta 1-3Gal beta 1-4Glc beta 1]n whose structure corresponds to that of the capsular polysaccharide of Streptococcus pneumoniae type 14, is described, involving a stereospecific polycondensation of the tetrasaccharide monomer, deacylation, and N-acetylation.
authors: N E
authors: NE
authors: Nifant'ev
authors: L V
authors: LV
authors: Bakinovskiĭ
authors: N K
authors: NK
authors: Kochetkov
mesh_terms: D002236:Carbohydrate Conformation; D002240:Carbohydrate Sequence; D002473:Cell Wall / Q000276:immunology; D055598:Chemical Phenomena; D002621:Chemistry; D009682:Magnetic Resonance Spectroscopy; D011135:Polysaccharides, Bacterial / Q000032:analysis / Q000138:chemical synthesis*; D013296:Streptococcus pneumoniae / Q000276:immunology*
chemical_list: D011135:Polysaccharides, Bacterial
vernacular_title: Sintez kapsuliarnogo polisakharida Streptococcus pneumoniae, tip 14. 4. Polikondensatsiia monomera i kharakteristika polisakharida.