title: [Study of complex lipids. Synthesis of diphosphatidylglycerol (cardiolipin) with unsaturated fatty acid residues].
abstract: Diphosphatidylglycerol (cardiolipin) with different fatty acid residues has been synthesised by condensation of 1,2-diacyl-sn-glycero-3-phosphoric acid (obtained, e.g., by the cabbage phospholipase D cleavage of 1,2-dioleyl-sn-glycero-3-phosphocholine or egg phosphatidylcholine) with 2-O-tert-butyldimethylsilylglycerol in the presence of 2,4,6-triisopropylbenzenesulphonylchloride. The synthetic cardiolipins as unsonicated aqueous calcium-free dispersions were shown, by means of 31P NMR spectroscopy, to form aggregates of the bilayer structure.
authors: I M
authors: IM
authors: Mishina
authors: I A
authors: IA
authors: Vasilenko
authors: A E
authors: AE
authors: Stepanov
authors: V I
authors: VI
authors: Shvets
mesh_terms: D002308:Cardiolipins / Q000138:chemical synthesis*; D055598:Chemical Phenomena; D002621:Chemistry; D002855:Chromatography, Thin Layer; D005231:Fatty Acids, Unsaturated; D009682:Magnetic Resonance Spectroscopy; D013010:Sonication; D013055:Spectrophotometry, Infrared
chemical_list: D002308:Cardiolipins; D005231:Fatty Acids, Unsaturated
vernacular_title: Issledovaniia v oblasti slozhnykh lipidov. Sintez difosfatidilglitserina (kardiolipina) s nenasyshchennymi zhirnokislotnymi ostatkami.