Thermal 7-9 transglycosylation of purine nucleosides and their analogues.
A novel thermal 7 in equilibrium 9 transglycosylation reaction was studied in the series of fully acetylated purine ribonucleosides and their 2-acetoxyethoxymethyl analogues. Ratio 7- to 9-isomers in the resultant mixtures was determined by the proton magnetic resonance spectroscopy.
Institute of Bio-organic Chemistry, Polish Academy of Sciences, Poznań.
J
J
Boryski
B
B
Golankiewicz
D006027:Glycosides; D006358:Hot Temperature; D007202:Indicators and Reagents; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D011684:Purine Nucleosides; D013329:Structure-Activity Relationship
D006027:Glycosides; D007202:Indicators and Reagents; D011684:Purine Nucleosides