Picosecond geminate recombination of nitrosylmyoglobins.
The kinetics of NO geminate recombination to sperm whale and elephant myoglobins has been studied on the picosecond time scale using an amplified colliding-pulse mode-locked ring dye laser. The dynamics of ligand rebinding are shown to be affected by the distal structure of the protein surrounding the heme pocket.
D000818:Animals; D004606:Elephants; D007700:Kinetics; D008024:Ligands; D009211:Myoglobin / Q000031:analogs & derivatives* / Q000032:analysis; D013053:Spectrophotometry; D014907:Whales
D008024:Ligands; D009211:Myoglobin; C031560:myoglobin nitroxide