title: Gas chromatographic data for 187 nitrogen- or phosphorus-containing drugs and metabolites of toxicological interest analysed on methyl silicone capillary columns.
abstract: Retention data, retention indices and retention times relative to diazepam, associated with 187 nitrogen- or phosphorus-containing drugs and metabolites likely to be found in toxicological analysis, are presented. The work was carried out with cross-linked methyl silicone, siloxane-deactivated fused-silica capillary columns in different gas chromatographs equipped with nitrogen-phosphorus flame ionization detectors and a gas chromatograph-mass spectrometer. Results show the high reproducibility offered by the capillary system, which permits the reduction of identification problems and analysis time.
mesh_terms: D055598:Chemical Phenomena; D002621:Chemistry; D002849:Chromatography, Gas; D064420:Drug-Related Side Effects and Adverse Reactions; D008401:Gas Chromatography-Mass Spectrometry; D009584:Nitrogen / Q000032:analysis; D009943:Organophosphorus Compounds / Q000032:analysis; D004364:Pharmaceutical Preparations / Q000032:analysis*
chemical_list: D009943:Organophosphorus Compounds; D004364:Pharmaceutical Preparations; D009584:Nitrogen