Undecagold clusters for site-specific labeling of biological macromolecules: simplified preparation and model applications.
We report simple and rapid procedures for the synthesis of a variety of stable, water-soluble undecagold cluster, and model applications of a thiol-reactive gold cluster for the specific labeling of cysteine residues in proteins.
D000818:Animals; D006046:Gold / Q000032:analysis*; D008024:Ligands; D046911:Macromolecular Substances; D009682:Magnetic Resonance Spectroscopy; D008956:Models, Chemical; D050607:Organogold Compounds; D009942:Organometallic Compounds / Q000032:analysis*; D011506:Proteins / Q000032:analysis; D013056:Spectrophotometry, Ultraviolet; D013438:Sulfhydryl Compounds / Q000032:analysis
D008024:Ligands; D046911:Macromolecular Substances; D050607:Organogold Compounds; D009942:Organometallic Compounds; D011506:Proteins; D013438:Sulfhydryl Compounds; C035797:undecagold; D006046:Gold