[Gas chromatographic determination of amino acid configuration in the optically active stationary phase].
The synthesis and physico-chemical properties of a novel optically active stationary phase--N-stearoyl-L-valyl-t-butylamide (I) applied for GLC separation of enantiomeric alpha-amino acids are described. The optical purity of the compound (I) is not less than 85%. The efficiency of the phase is shown on analyses of the configuration of amino acids in peptidolipids and glycopeptidolipids produced by the paraffin-oxidizing bacterium Mycobacterium paraffinicum.
D000595:Amino Acid Sequence; D000596:Amino Acids / Q000032:analysis*; D055598:Chemical Phenomena; D002627:Chemistry, Physical; D002849:Chromatography, Gas / Q000379:methods; D006017:Glycolipids / Q000032:analysis; D006020:Glycopeptides / Q000032:analysis; D013058:Mass Spectrometry; D009161:Mycobacterium / Q000032:analysis; D011510:Proteolipids / Q000032:analysis
D000596:Amino Acids; D006017:Glycolipids; D006020:Glycopeptides; D011510:Proteolipids
Gazokhromatograficheskoe opredelenie konfiguratsii aminokislot na opticheski aktivnoĭ statsionarnoĭ faze.