Reverse Königs-Knorr reaction. Synthesis of beta-D-gluco-thio-cerebroside.
The synthesis of 1-thio-beta-D-glucocerebroside by reaction of 1-iodo-3-O-benzoylceramide with 1-mercapto-beta-D-glucopyranose in the presence of sterically hindered amine (DBU) is described.
D002554:Cerebrosides / Q000138:chemical synthesis*; D055598:Chemical Phenomena; D002621:Chemistry
C047853:(beta-glucopyranosyl)-1-thiocerebroside; D002554:Cerebrosides