Direct evidence for carbanions and covalent N 5 -flavin-carbanion adducts as catalytic intermediates in the oxidation of nitroethane by D-amino acid oxidase.
D000605:Amino Alcohols; D000818:Animals; D002247:Carbon Isotopes; D002384:Catalysis; D003486:Cyanides; D003605:D-Amino-Acid Oxidase / Q000037:antagonists & inhibitors; D004355:Drug Stability; D004980:Ethane; D005182:Flavin-Adenine Dinucleotide; D005415:Flavins; D005420:Flavoproteins; D005609:Free Radicals; D006863:Hydrogen-Ion Concentration; D007668:Kidney / Q000201:enzymology; D007700:Kinetics; D008433:Mathematics; D008956:Models, Chemical; D009574:Nitro Compounds; D009994:Osmolar Concentration; D010084:Oxidation-Reduction; D010101:Oxygen Consumption; D011188:Potassium; D013552:Swine; D013696:Temperature
D000605:Amino Alcohols; D002247:Carbon Isotopes; D003486:Cyanides; D005415:Flavins; D005420:Flavoproteins; D005609:Free Radicals; D009574:Nitro Compounds; D005182:Flavin-Adenine Dinucleotide; D003605:D-Amino-Acid Oxidase; D004980:Ethane; D011188:Potassium