Water-soluble metabolites of p-nitrophenol and 1-naphthyl N-methylcarbamate in flies and grass grubs. Formation of glucose phosphate and phosphate conjugates.
Metabolites isolated from houseflies dosed with 1-napththol or p-nitrophenol were identified as the phosphate and glucose phosphate conjugates of these phenols by titrations, hydrolysis, ionophoresis, i.r. spectra and mixed melting point. [(3)H]Carbaryl (1-naphthyl N-methylcarbamate) was metabolized by houseflies, blowflies and grass grubs to water-soluble metabolites which had chromatographic and ionophoretic behaviour similar to those of the conjugates of 1-naphthol with glucose, sulphate, phosphate and glucose 6-phosphate.
D000818:Animals; D002219:Carbamates / Q000302:isolation & purification; D012721:Carbaryl / Q000378:metabolism*; D002854:Chromatography, Paper; D001517:Coleoptera / Q000378:metabolism*; D004175:Diptera / Q000378:metabolism*; D005958:Glucosephosphates / Q000302:isolation & purification / Q000378:metabolism; D007478:Iontophoresis; D009284:Naphthols / Q000302:isolation & purification / Q000378:metabolism*; D009596:Nitrophenols / Q000302:isolation & purification / Q000378:metabolism*; D010710:Phosphates / Q000302:isolation & purification / Q000378:metabolism
D002219:Carbamates; D005958:Glucosephosphates; D009284:Naphthols; D009596:Nitrophenols; D010710:Phosphates; D012721:Carbaryl