Absolute configuration of a metabolite in the m-fission pathway of protocatechuate.
An aldolase, which is induced in Pseudomonas testosteroni during growth with p-hydroxybenzoate, preferentially attacks the R form of 4-hydroxy-4-methyl-2-oxoglutarate, a metabolite of protocatechuate catabolism.
D000645:Ammonium Sulfate; D001565:Benzoates / Q000378:metabolism*; D002384:Catalysis; D002474:Cell-Free System; D011232:Chemical Precipitation; D002848:Chromatography, DEAE-Cellulose; D003035:Cobalt; D005470:Fluorometry; D005634:Fructose-Bisphosphate Aldolase / Q000302:isolation & purification / Q000378:metabolism*; D005977:Glutarates / Q000032:analysis / Q000096:biosynthesis / Q000378:metabolism*; D007770:L-Lactate Dehydrogenase / Q000378:metabolism; D008293:Malates / Q000096:biosynthesis; D008968:Molecular Conformation; D009243:NAD / Q000378:metabolism; D009904:Optical Rotation; D011479:Protamines; D011549:Pseudomonas / Q000201:enzymology* / Q000378:metabolism; D011773:Pyruvates / Q000096:biosynthesis; D013237:Stereoisomerism
D001565:Benzoates; D005977:Glutarates; D008293:Malates; D011479:Protamines; D011773:Pyruvates; D009243:NAD; D003035:Cobalt; D007770:L-Lactate Dehydrogenase; D005634:Fructose-Bisphosphate Aldolase; D000645:Ammonium Sulfate