Mechanism for chiral recognition of a prochiral center and for amino acid complexation to a cobalt(3) tetramine. The crystal structure, absolute configuration, and circular dichroism of lambda(-)436-beta2-(2S,9S)-2,9-diamino-4,7-diazadecanecobalt(3) aminomethylmalonate) perchlorate monohydrate.
D000599:Amino Acids, Diamino; D001372:Aza Compounds; D002942:Circular Dichroism; D003035:Cobalt; D006863:Hydrogen-Ion Concentration; D008314:Malonates; D008968:Molecular Conformation; D011073:Polyamines; D014961:X-Ray Diffraction
D000599:Amino Acids, Diamino; D001372:Aza Compounds; D008314:Malonates; D011073:Polyamines; D003035:Cobalt