De novo synthesis of glycosidic linkages by glycosylases: utilization of  -D-glucopyranosyl fluoride by amylosucrase.
D005459:Fluorides; D005632:Fructose; D005947:Glucose; D005964:Glucosyltransferases; D011134:Polysaccharides / Q000096:biosynthesis
D011134:Polysaccharides; D005632:Fructose; D005964:Glucosyltransferases; D005947:Glucose; D005459:Fluorides