title: The origin and structures of dimeric fatty acids from the anaerobic reaction between soya-bean lipoxygenase, linoleic acid and its hydroperoxide.
abstract: In an anaerobic system soya-bean lipoxygenase catalyses in the presence of linoleic acid and l-13-hydroperoxyoctadeca-cis-9-trans-11-dienoic acid the formation of dimeric fatty acids and of carbonyl compounds. The analogous reaction does not take place when d-9-hydroperoxyoctadeca-trans-10-cis-12-dienoic acid is used instead of the 13-hydroperoxy isomer. Non-oxygenated dimers stem directly from linoleic acid and have C((11))-C((13')) or -C((9')) and C((13))-C((13')) or -C((9')) linkages. Dimers that contain oxygen originate from linoleic acid and linoleic acid hydroperoxide. It is most likely that the oxygen is present in epoxy groups.
mesh_terms: D000693:Anaerobiosis; D002247:Carbon Isotopes; D002855:Chromatography, Thin Layer; D004988:Ethers, Cyclic; D005227:Fatty Acids; D008041:Linoleic Acids; D013058:Mass Spectrometry; D008956:Models, Chemical; D010105:Oxygenases; D010545:Peroxides; D011108:Polymers; D013025:Glycine max; D013053:Spectrophotometry
chemical_list: D002247:Carbon Isotopes; D004988:Ethers, Cyclic; D005227:Fatty Acids; D008041:Linoleic Acids; D010545:Peroxides; D011108:Polymers; D010105:Oxygenases