Inversions of both adjacent centers in the formolysis of a 2,2,6-trialkylcyclohexyl tosylate. Formation of a 13 -D-homo steroid.
D000478:Alkylation; D000731:Androstanes / Q000138:chemical synthesis*; D003510:Cyclohexanes; D005561:Formates; D006718:Homosteroids / Q000138:chemical synthesis*; D008722:Methods; D011278:Pregnanes; D013329:Structure-Activity Relationship; D014105:Tosyl Compounds
D000731:Androstanes; D003510:Cyclohexanes; D005561:Formates; D006718:Homosteroids; D011278:Pregnanes; D014105:Tosyl Compounds