title: Total synthesis of acetate from CO2. VII. Evidence with Clostridium thermoaceticum that the carboxyl of acetate is derived from the carboxyl of pyruvate by transcarboxylation and not by fixation of CO2.
mesh_terms: D000085:Acetates / Q000096:biosynthesis*; D002087:Butyrates / Q000378:metabolism; D002245:Carbon Dioxide / Q000378:metabolism* / Q000494:pharmacology; D002247:Carbon Isotopes; D002474:Cell-Free System; D003013:Clostridium / Q000187:drug effects / Q000201:enzymology / Q000378:metabolism*; D005288:Ferredoxins / Q000378:metabolism; D007553:Isotope Labeling; D007651:Keto Acids / Q000378:metabolism; D007700:Kinetics; D008745:Methylation; D010084:Oxidation-Reduction; D010088:Oxidoreductases / Q000378:metabolism; D011773:Pyruvates / Q000378:metabolism*; D013056:Spectrophotometry, Ultraviolet; D013763:Tetrahydrofolates / Q000378:metabolism; D013997:Time Factors; D014805:Vitamin B 12 / Q000378:metabolism
chemical_list: D000085:Acetates; D002087:Butyrates; D002247:Carbon Isotopes; D005288:Ferredoxins; D007651:Keto Acids; D011773:Pyruvates; D013763:Tetrahydrofolates; D002245:Carbon Dioxide; D010088:Oxidoreductases; D014805:Vitamin B 12