An anaerobic reaction between lipoxygenase, linoleic acid and its hydroperoxides.
In an anaerobic system soya-bean lipoxygenase together with linoleic acid induces a structural rearrangement of 13-hydroperoxyoctadeca-cis-9-trans-11-dienoic acid leading to the formation of 13-oxotrideca-cis(trans)-9-trans-11-dienoic acid and n-pentane as well as 13-oxo-octadeca-9,11-dienoic acid. It is proposed that the 13-peroxyoctadeca-cis-9-trans-11-dienoic acid radical formed through hydrogen radical abstraction by the linoleic acid radical is the key intermediate for these reactions.
D000447:Aldehydes; D000693:Anaerobiosis; D002855:Chromatography, Thin Layer; D007659:Ketones; D008041:Linoleic Acids; D013058:Mass Spectrometry; D010100:Oxygen / Q000032:analysis; D010105:Oxygenases; D010545:Peroxides; D013025:Glycine max; D013053:Spectrophotometry
D000447:Aldehydes; D007659:Ketones; D008041:Linoleic Acids; D010545:Peroxides; D010105:Oxygenases; D010100:Oxygen