title: Demonstration of a change in the rate-determining step in papain- and ficin-catalyzed acyl-transfer reactions.
mesh_terms: D000215:Acylation; D000577:Amides; D001593:Benzyl Compounds; D055598:Chemical Phenomena; D002621:Chemistry; D010450:Endopeptidases; D004789:Enzyme Activation; D004952:Esters; D005561:Formates; D005998:Glycine; D006626:Hippurates; D006639:Histidine; D006863:Hydrogen-Ion Concentration; D007700:Kinetics; D008433:Mathematics; D009596:Nitrophenols; D009994:Osmolar Concentration; D010206:Papain; D011485:Protein Binding; D013053:Spectrophotometry; D013885:Thiosulfates; D014364:Tryptophan
chemical_list: D000577:Amides; D001593:Benzyl Compounds; D004952:Esters; D005561:Formates; D006626:Hippurates; D009596:Nitrophenols; D013885:Thiosulfates; D006639:Histidine; D014364:Tryptophan; D010450:Endopeptidases; D010206:Papain; D005998:Glycine