Binuclear ion containing nitrogen as a bridging group.
A binuclear ion ([NH(3))5RuN(2)Ru(NH(3))(5)](5)+ is formed by the direct reaction of N(2) with an aqueous solution of (NH(3))(5)RuOH(2)(2+) at room temperature. The binuclear ion is also formed by the reversible reaction of (NH(3))5RuOH(2)(2+) with (NH(3))(5)RuN(2)(2+). Solid [(NH(3))(5)RuN(2)Ru(NH(3))(5)] (BF(4))(4) has been prepared, and its ultraviolet and infrared spectra are reported.
D055598:Chemical Phenomena; D002621:Chemistry; D007259:Infrared Rays; D007477:Ions; D009584:Nitrogen; D000644:Quaternary Ammonium Compounds; D012428:Ruthenium; D012996:Solutions; D013057:Spectrum Analysis; D014466:Ultraviolet Rays
D007477:Ions; D000644:Quaternary Ammonium Compounds; D012996:Solutions; D012428:Ruthenium; D009584:Nitrogen