Synthesis and desulfurization-decarboxylation of cyclic thionocarbonates of glycerol 1-ethers.
A method is described for the synthesis of cyclic thionocarbonates of 1-O-alkyl glycerols in quantitative yield. These derivatives of glycerol ethers can be quantitated by UV absorbance, analyzed by gas-liquid chromatography, or quantitatively converted to allyl alkyl ethers for gas-chromatographic analysis.
D000438:Alcohols; D002254:Carbonates / Q000138:chemical synthesis*; D055598:Chemical Phenomena; D002621:Chemistry; D002849:Chromatography, Gas; D002855:Chromatography, Thin Layer; D004987:Ethers; D005990:Glycerol; D006571:Heterocyclic Compounds; D007259:Infrared Rays; D008722:Methods; D013057:Spectrum Analysis; D013455:Sulfur; D014466:Ultraviolet Rays
D000438:Alcohols; D002254:Carbonates; D004987:Ethers; D006571:Heterocyclic Compounds; D013455:Sulfur; D005990:Glycerol