The gem effect. 3. The influence of 3-mono- and 3-gem substitution on the acid dissociation constants of glutaric acid. A comparison of the sensitivity of delta-pK-a of dicarboxylic acids and the rate of ring closure of their monoesters to the intramolecular distance separating carboxyl functions.
D055598:Chemical Phenomena; D002621:Chemistry; D003998:Dicarboxylic Acids; D005977:Glutarates
D003998:Dicarboxylic Acids; D005977:Glutarates