Detection and study by fluorescence spectrometry of stereospecificity in mushroom tyrosinase-catalyzed oxidations. Proposal of a copper-containing reaction rate control site.
D001487:Basidiomycota / Q000201:enzymology; D002384:Catalysis; D055598:Chemical Phenomena; D002621:Chemistry; D003300:Copper; D004295:Dihydroxyphenylalanine / Q000378:metabolism*; D004298:Dopamine / Q000378:metabolism; D004837:Epinephrine / Q000378:metabolism*; D005470:Fluorometry; D066298:In Vitro Techniques; D007700:Kinetics; D009638:Norepinephrine / Q000378:metabolism*; D014445:Tyrosine Decarboxylase / Q000378:metabolism*
D004295:Dihydroxyphenylalanine; D003300:Copper; D014445:Tyrosine Decarboxylase; D004298:Dopamine; D009638:Norepinephrine; D004837:Epinephrine