[Study of radicals formed in the interaction of organic hydroperoxides with ferric ions using the spin trap method].
The mechanism of free radical generation in the reaction of ferrous ion with t-butyl and linolenic acid hydroperoxide was investigated by spin trapping method. The t-butoxyl, methyl, linolenic acid alkoxyl and alkyl radical spin adducts EPR spectra were observed and identified.
D003497:Cyclic N-Oxides; D004578:Electron Spin Resonance Spectroscopy; D005609:Free Radicals; D007477:Ions; D007501:Iron; D008042:Linolenic Acids; D008054:Lipid Peroxides; D009589:Nitrogen Oxides; D010084:Oxidation-Reduction; D010545:Peroxides; D013113:Spin Labels; D017962:alpha-Linolenic Acid; D020122:tert-Butylhydroperoxide
D003497:Cyclic N-Oxides; D005609:Free Radicals; D007477:Ions; D008042:Linolenic Acids; D008054:Lipid Peroxides; D009589:Nitrogen Oxides; D010545:Peroxides; D013113:Spin Labels; D017962:alpha-Linolenic Acid; C025998:13-hydroperoxylinolenic acid; C029217:phenyl-N-tert-butylnitrone; D020122:tert-Butylhydroperoxide; D007501:Iron
Issledovanie radikalov, obrazuiushchikhsia pri vzaimodeĭstvii organicheskikh gidroperekiseĭ s ionami zheleza, metodom spinovykh lovushek.