[Structure of the carbohydrate moiety of carminomycins II and III].
Saccharides II and III were obtained on catalytic hydrogenolysis of carminomycins II and III. The saccharides contained daunosamine and a nitrogen-free fragment of unknown structure. Crotonic aldehyde in the form of 2,4-dinitrophenylhydrazone and 1,2-propylenglycol in the form of 3,5-dinitrobenzoate were isolated on acid hydrolysis of the saccharides. The study on the chemical and spectral properties (PMR-spectra) of the saccharides, their N,O-acetates and hydrolysis products suggested the structure of th carbohydrate moiety of carminomycins II and III as a disaccharide of daunosamine and acyclic semiacetal of 2,4-desoxytetrose.
D002241:Carbohydrates / Q000032:analysis*; D002360:Carubicin / Q000032:analysis*; D055598:Chemical Phenomena; D002621:Chemistry; D002845:Chromatography; D003630:Daunorubicin / Q000031:analogs & derivatives*; D004578:Electron Spin Resonance Spectroscopy; D013055:Spectrophotometry, Infrared
D002241:Carbohydrates; D002360:Carubicin; D003630:Daunorubicin
Struktura uglevodnoĭ chasti karminomitsinov II i III.