Method for analysis of polybrominated biphenyls by gas chromatography mass spectrometry.
Gas chromatography using a short packed column (45 cm, 0.2 cm i.d., 2% OV-101 on Gas-Chrom Q) with mass spectrometric detection in the selected ion monitoring mode has been found satisfactory for the analysis of lower as well as higher polybrominated biphenyls. Acceptable sensitivity (< 1 ng) may be achieved for this method by focusing selectively at either the low (m/z 20-600) or the high m/z 600-1000) range of the quadrupole filter (low range for mono- through hexabromobiphenyl, high range for hexa- through decabromobiphenyl). A tuning technique has been developed for low range and high range polybrominated biphenyls using the ion abundances of perfluorotributylamine as a standard. Standard ions for the quantitation of mono- through decabromo-biphenyls were selected and validated. The technique was applied to the analysis of a variety of environmental samples.
D000818:Animals; D001713:Biphenyl Compounds / Q000032:analysis*; D005399:Fishes; D008401:Gas Chromatography-Mass Spectrometry / Q000379:methods; D010944:Plants / Q000032:analysis; D011075:Polybrominated Biphenyls / Q000032:analysis*; D012987:Soil / Q000032:analysis
D001713:Biphenyl Compounds; D011075:Polybrominated Biphenyls; D012987:Soil