title: An approach to the mechanism of the asymmetrical radical formation in yttrium-90-beta-irradiated D- and L-alanines.
abstract: Several attempts were made to investigate the mechanism of the asymmetrical radical formation in yttrium-90-beta-irradiated D- and L-alanines which was reported in the preceding paper (1). The experiments demonstrated that the magnitude of the asymmetry was dependent on beta-ray dose, namely the lower the dose the larger the observed difference was, and that no difference could be detected when the alanines were irradiated in aqueous state. The results in the present study seem to that different interaction between the crystal structure of the two enantiomers and polarized beta-rays may be responsible for the observed phenomenon.
mesh_terms: D000409:Alanine / Q000528:radiation effects*; D004307:Dose-Response Relationship, Radiation; D004578:Electron Spin Resonance Spectroscopy; D005609:Free Radicals; D013237:Stereoisomerism; D015021:Yttrium Radioisotopes
chemical_list: D005609:Free Radicals; D015021:Yttrium Radioisotopes; D000409:Alanine