The specific capsular polysaccharide of Streptococcus pneumoniae type 9V.
The specific capsular polysaccharide produced by Streptococcus pneumoniae type 9V (American type 68) is composed of D-glucuronic acid (1 part), D-galactose (1 part), 2-acetamido-2-deoxy-D-mannose (1 part), D-glucose (2 parts), and O-acetyl (1.6 parts). Methylation, periodate oxidation, optical rotation, and nuclear magnetic resonance studies, and partial hydrolysis showed that the polysaccharide is an unbranched high molecular weight linear polymer of a partially O-acetylated pentasaccharide repeating unit having the structure indicated below. (Formula: see text).
D055598:Chemical Phenomena; D002621:Chemistry; D005690:Galactose / Q000032:analysis; D005947:Glucose / Q000032:analysis; D005965:Glucuronates / Q000032:analysis; D020723:Glucuronic Acid; D006595:Hexosamines / Q000032:analysis; D006868:Hydrolysis; D009682:Magnetic Resonance Spectroscopy; D008358:Mannose / Q000031:analogs & derivatives / Q000032:analysis; D008745:Methylation; D010084:Oxidation-Reduction; D010504:Periodic Acid; D011135:Polysaccharides, Bacterial / Q000032:analysis*; D013296:Streptococcus pneumoniae / Q000032:analysis*
D005965:Glucuronates; D006595:Hexosamines; D011135:Polysaccharides, Bacterial; D010504:Periodic Acid; C008322:mannosamine; D020723:Glucuronic Acid; D005947:Glucose; D008358:Mannose; D005690:Galactose