Synthesis, structure, and features of anilinium anilinomethanesulfonates.
Two series of anilinomethanesulfonate derivatives, the anilinium and p-toluidinium anilinomethanesulfonates, were synthesized. They present interesting spectroscopic features and can be used as characteristic derivatives of the parent compounds. These series allow the easy study of the N--H stretching frequencies of the secondary amine whereas difficulties are encountered with the parent compounds due to the occurrence of O--H stretching bands in the same frequency range. All three compounds present a common fragmentation pattern in mass spectral analysis. Through these analyses, the salt structure of the anilinium anilinomethanesulfonates is demonstrated in opposition to a sulfonamide structure, giving further support to the salt structure of other series previously reported.
D055598:Chemical Phenomena; D002621:Chemistry; D013058:Mass Spectrometry; D008698:Mesylates / Q000138:chemical synthesis*; D013055:Spectrophotometry, Infrared
D008698:Mesylates; C032988:anilinomethanesulfonate