Allyl derivatives of zearalenone.
The Claisen rearrangement of 4-O-allylzearalenone led to only one principal product, which was identified as 3-allylzearalenone with the aid of photochemical isomerization and PMR spectroscopy. This general method is useful for distinguishing 3-substituted zearalenone isomers from 5-substituted isomers. Hydrogenation of 3-allylzearalenone gave 3-(1-propyl)zearalanone.
D055598:Chemical Phenomena; D002621:Chemistry; D007536:Isomerism; D012118:Resorcinols / Q000138:chemical synthesis*; D015025:Zearalenone / Q000031:analogs & derivatives / Q000138:chemical synthesis*
D012118:Resorcinols; D015025:Zearalenone