Aromatic retinal analogues and their interaction with cattle opsin.
The preparation of seven aromatic analogues of retinal, the isolation and characterization of their geometric isomers, and the interaction of these isomers with cattle opsin are reported. Within certain limitations, it has been demonstrated that stable aromatic rhodopsin analogues can be prepared. In general, the stereoselectivity of isomers of these compounds in their interaction with opsin and the absorption properties of the resultant pigments are similar to those of the parent retinal.
D000818:Animals; D002417:Cattle; D005136:Eye Proteins; D007536:Isomerism; D009682:Magnetic Resonance Spectroscopy; D010786:Photoreceptor Cells; D012172:Retinaldehyde / Q000031:analogs & derivatives*; D012243:Rhodopsin / Q000031:analogs & derivatives; D017299:Rod Opsins; D013056:Spectrophotometry, Ultraviolet; D014801:Vitamin A / Q000031:analogs & derivatives*
D005136:Eye Proteins; D017299:Rod Opsins; D014801:Vitamin A; D012243:Rhodopsin; D012172:Retinaldehyde