Persistence of fensulfothion in a sandy-loam soil and uptake by rutabagas, carrots and radishes using microplots.
Field microplots were treated with 141 and 282 ppm fensulfothion and 37.1 and 74.2 ppm fensulfothion sulfone. These concentrations are equivalent to field treatment rates of 8.48 and 16.96 kg AI/ha, fensulfothion, and 2.23 and 4.47 kg AI/ha, fensulfothion sulfone, respectively, for banded application (10 cm wide, rows 80 cm apart). The half-lives in a sandy loam soil were 30-39 and 14-23 days, respectively. Fensulfothion sulfone and sulfide were the main derivatives found in fensulfothion treated soil. The maximum levels of these derivatives were 21.22 and 22.95 ppm, respectively for the 8.48 kg/ha treatment and 33.90 and 42.45 ppm, respectively, for the higher treatment, which occurred between 30-60 days. Carrots appeared to take up more fensulfothion from soil than rutabagas or radishes. The residue levels at harvest decreased in the order carrot peel greater than pulp greater than rutabagas root greater than peel greater than pulp. Residue levels of fensulfothion and sulfone in radishes were similar to those found in rutabagas. The ratio sulfoxide/sulfone in rutabagas ranged from 0.4-1.5 and in carrots from 1.7-7.6. This phenomenon is thought to be due to oxidative enzyme systems present in rutabagas. Dimethyl phosphorothioic acid, but not dimethyl phosphoric acid was detected (max. 1.33 ppm) in some rutabagas samples but not in carrots.
D001937:Brassica / Q000378:metabolism; D004305:Dose-Response Relationship, Drug; D004355:Drug Stability; D006207:Half-Life; D007306:Insecticides / Q000032:analysis*; D009946:Organothiophosphorus Compounds / Q000031:analogs & derivatives / Q000032:analysis* / Q000378:metabolism; D010573:Pesticide Residues / Q000032:analysis; D010945:Plants, Edible / Q000378:metabolism; D012989:Soil Pollutants / Q000032:analysis*; D014675:Vegetables / Q000032:analysis*
D007306:Insecticides; D009946:Organothiophosphorus Compounds; D010573:Pesticide Residues; D012989:Soil Pollutants; C031114:fensulfothion sulfone; C031115:fensulfothion sulfide