Preparation of 2,3-seco-5 alpha-cholestane-2,3-diol and 4 alpha-methyl-2,3-seco-5 alpha-cholestane-2,3-diol and its reactions with o-nitrophenyl selenocyanate.
The reaction of 2,3-seco-5 alpha-cholestane-2,3-diol and 4 alpha-methyl-2,3-seco-5 alpha-cholestane-2,3-diol with o-nitrophenyl selenocyanate was studied. The diols were synthesized from cholesterol.
D055598:Chemical Phenomena; D002621:Chemistry; D002777:Cholestanols / Q000138:chemical synthesis*; D007202:Indicators and Reagents; D009682:Magnetic Resonance Spectroscopy; D009570:Nitriles; D009904:Optical Rotation; D012632:Secosteroids / Q000138:chemical synthesis*; D013055:Spectrophotometry, Infrared
D002777:Cholestanols; D007202:Indicators and Reagents; D009570:Nitriles; D012632:Secosteroids; C044302:2,3-secocholestane-2,3-diol; C044301:2-nitrophenyl selenocyanic acid; C044303:4-methyl-2,3-secocholestane-2,3-diol