[The synthesis of valperinol and various 3-aminomethyl derivatives of 2,9-dioxatricyclo[4,3,1,0(3,7)]decane from didrovaltrate].
3-Aminomethyl derivatives of 2,9-dioxatricyclo [4,3,1,0(3,7)]decane, can be synthesized via an amination, starting from (1R, 3S, 4S, 6R, 7S, 8R, 10R)-3-iodomethyl-4-acetoxy-8-methoxy-10-methyl-2, 9-dioxatricyclo [4,3,1,0(3,7)]decane or (1R, 3S, 4S, 6R, 7S, 8R)-3-iodomethyl-4-acetoxy-8-methoxy-10-methylen-2,9- dioxatricyclo [4,3,1,0(3,7)]decane, which can be prepared from didrovaltrate.
D001952:Bridged-Ring Compounds; D055598:Chemical Phenomena; D002621:Chemistry; D039823:Iridoids; D010880:Piperidines / Q000138:chemical synthesis*; D011714:Pyrans
D001952:Bridged-Ring Compounds; D039823:Iridoids; D010880:Piperidines; D011714:Pyrans; C044308:valperinol; C024750:didrovaltrate
Synthese von Valperinol und einigen 3-Aminomethyl-Derivaten des 2,9-Dioxatricyclo[4,3,1,0(3,7)]decans aus Didrovaltrat.