Correlation between microstructure of Ag-Pd-Au-Cu alloy and changes in shape on aging.
An investigation has been carried out to study changes in shape on aging in plastic deformed Ag-Pd-Au-Cu alloys. The changes in shape were measured in order to establish a relationship to the aging heat treatments. Their microstructure was observed in order to clarify this phenomenon at the same time. They were also investigated quantitatively using a feature analysis system. The changes in shape were interpreted as the shrinkage in volume resulting from the formation of the ordered phase. They were smaller at aging temperatures below 673 K. The change in microstructure was different at aging temperature between 573 and 773 K. These phenomena were due to the following: First, nodules which nucleated at the grain boundaries would have grown into the grains well before the formation of the ordered phase, and second, the shrinkage in volume would have been of a different kind that the ordered phase. Therefore aging treatments should be carried out at low temperature in order to minimize the changes in shape. Also, nodular growth should be inhibited in order to maximize the hardening in Ag-rich alloys.
D000497:Alloys / Q000032:analysis*; D003300:Copper / Q000032:analysis; D006046:Gold / Q000032:analysis; D006244:Hardness; D007854:Lead / Q000032:analysis; D010316:Particle Size; D012834:Silver / Q000032:analysis; D013997:Time Factors
D000497:Alloys; D007854:Lead; D012834:Silver; D006046:Gold; D003300:Copper