[Semisynthetic cerebrosides].
Psychosine prepared from bovine brain cerebroside was used for synthesis of galactosphingolipids with DL-, D-, or L-2-hydroxyhexadecanoic acids and 6-(2'-anthroyl) hexanoic acid. Psychosine was N-acetyl with p-nitrophenyl 2-acetoxyhexadecanoates in the presence of hydroxybenzotriazole to give cerebrosides. The 6-(2'-anthroyl)hexanoic acid reaction with psychosine was effected via its acyl chloride.
D000818:Animals; D001923:Brain Chemistry; D002417:Cattle; D002554:Cerebrosides / Q000138:chemical synthesis* / Q000302:isolation & purification; D008722:Methods
D002554:Cerebrosides
Polusinteticheskoe poluchenie tserebrozidov.