Corrosion of resin-bonded orthodontic brackets.
The objective was to identify the nature and origin of indelible black and green stains found in enamel after the removal of bonded orthodontic brackets. Several brackets were examined by scanning electron microscopy and energy-dispersive x-ray analysis. Irrespective of the type of bracket or resin, morphologic evidence of corrosion activity was found. Brackets were pitted, and in some cases large amounts of metal were missing. Cracks were found in the resin which led to sites of destruction in which structures resembling microorganisms were also found. X-ray analysis showed the presence of chromium, nickel, iron, and chlorine in significant amounts in the bonding, discolored resin. It was concluded that the cracks were favoring crevice corrosion. In the presence of organisms and a lowered pH, together with a chloride environment and an oxygen gradient, conditions conducive to corrosion are established.
D055598:Chemical Phenomena; D002627:Chemistry, Physical; D003188:Composite Resins / Q000009:adverse effects*; D003343:Corrosion; D001840:Dental Bonding; D004577:Electron Probe Microanalysis; D006801:Humans; D008855:Microscopy, Electron, Scanning; D009967:Orthodontic Appliances / Q000009:adverse effects*; D013193:Stainless Steel; D014075:Tooth Discoloration / Q000209:etiology*
D003188:Composite Resins; D013193:Stainless Steel