Isolation of adenosine 5'-diphosphate-D-glycero-D-mannoheptose. An intermediate in lipopolysaccharide biosynthesis of Shigella sonnei.
From a Shigella sonnei R mutant which incorporates into its cell wall lipopolysaccharide D-glycero-D-mannoheptose and contains no L-glycero-D-mannoheptose, a nucleotide-linked sugar was isolated and identified as adenosine 5'-diphosphate-D-glycero-d-mannoheptose by chemical and chromatographic analysis. This intermediary compound is assumed to play a role in heptose biosynthesis of Enterobacteria.
D000247:Adenosine Diphosphate Sugars / Q000302:isolation & purification* / Q000378:metabolism; D002849:Chromatography, Gas; D002854:Chromatography, Paper; D002855:Chromatography, Thin Layer; D008070:Lipopolysaccharides / Q000096:biosynthesis*; D013058:Mass Spectrometry; D009702:Nucleoside Diphosphate Sugars / Q000302:isolation & purification*; D012764:Shigella sonnei / Q000378:metabolism*
D000247:Adenosine Diphosphate Sugars; D008070:Lipopolysaccharides; D009702:Nucleoside Diphosphate Sugars; C031557:adenosine 5'-diphosphate-glycero-mannoheptose