4-META opaque resin--a new resin strongly adhesive to nickel-chromium alloy.
1) A new adhesive opaque resin containing a reactive monomer, 4-methacryloxy-ethyl trimellitate anhydride (4-META), was prepared, and its application to thermosetting acrylic resin veneer crowns was studied. 2) The 4-META opaque resin was applied to a variety of nickel-chromium dental alloy specimens which had undergone different treatment, and endurance tests were conducted to evaluate the durability of adhesion. 3) Stable adhesion against water penetration was achieved with metal surfaces first etched with HCl and then oxidized with HNO3. A bond strength of 250 kg/cm2 was maintained even after immersion in water at 37 degrees C for 30 wk or at 80 degrees C for ten wk. Furthermore, this value did not decrease even after the specimens were subjected to 500 thermal cycles. 4) The 4-META opaque resin studied can eliminate the necessity for retention devices on metal castings. 5) The smooth 4-META opaque resin should have no adverse effects on gingivae.
D000179:Acrylates; D000180:Acrylic Resins; D000268:Adhesiveness; D002857:Chromium; D003722:Dental Alloys; D001840:Dental Bonding; D004853:Epoxy Resins; D008689:Methacrylates; D009532:Nickel; D013499:Surface Properties
D000179:Acrylates; D000180:Acrylic Resins; D003722:Dental Alloys; D004853:Epoxy Resins; D008689:Methacrylates; D002857:Chromium; C034139:4-methacryloxyethyltrimellitic acid anhydride; D009532:Nickel; C031172:4-META resin