Variability in the content and composition of alkaloid found in Canadian ergot. III. Triticale and barley.
The total alkaloid content and individual alkaloid composition were determined by colorimetry and high performance liquid chromatography, respectively, for Canadian triticale and barley ergot (Claviceps purpurea). The total alkaloid content was highly variable between individual sclerotia from the same or different sources and ranged from 0.042 to 0.752% for triticale and from 0.082 to 1.04% for barley; average values were 0.239% for Ottawa triticale, 0.289% for Prairie triticale, and 0.264% for barley. Ergocristine and its isomer ergocristinine were the major constituents in both grains. On average, Canadian ergot pooled from rye, wheat, triticale, and barley consists of ergocristine (31%), ergocristinine (13%), ergocristinine (13%), ergotamine (17%), ergotaminine (8%), ergocryptine (5%), ergocryptinine (3%), ergometrine (5%), ergometrinine (2%), ergosine (4%), ergostinine (2%), ergocornine (4%), ergocorninine (2%), and unidentified alkaloids (3%), and an average total alkaloid content of 0.236%. With the exception of rye and barley ergot from the maritime regions, Canadian rye, wheat, triticale, and barley ergot is fairly uniform in individual alkaloid composition.
D002170:Canada; D002967:Claviceps / Q000032:analysis*; D002523:Edible Grain / Q000382:microbiology*; D004876:Ergot Alkaloids / Q000032:analysis*; D001467:Hordeum / Q000382:microbiology*
D004876:Ergot Alkaloids