[Analysis of the methods of evaluation of occupational exposure to benzene and phenol of petrochemical industry workers].
209 workers exposed to airborne benzene and phenol at the Mazovian Refining Petrochemical Works, at three different plants, i.e. of Phenol, Gasoline Composing and Water -- Wastes, have been examined. It has been demonstrated that urine phenol content in workers working in an open plant area is very often inadequate to the airborne time-weighted averaged concentration of benzene and phenol. It has been shown more advisable to determine urine phenol concentrations twice: before and after the work shift. At the same time some specific methods have been recommended for determining phenol concentrations in urine. These are: gas chromatographic method of Dirmikis and Darbre, modified in this laboratory, and Gibbs' colorimetric method modified by Bardodej with 4-amino-antipyrine or Gibbs' colorimetric method with 2,6-dibromoquinone-4-chloroimide modified by Hanke et al. The Theis-Benedict method should not be applied in medical analytical laboratory because of its low specificity to phenol.
D000328:Adult; D000393:Air Pollutants / Q000032:analysis*; D000395:Air Pollutants, Occupational / Q000032:analysis*; D001554:Benzene / Q000032:analysis* / Q000652:urine; D002617:Chemical Industry; D002849:Chromatography, Gas; D003124:Colorimetry / Q000379:methods; D006801:Humans; D008297:Male; D008875:Middle Aged; D010578:Petroleum; D010636:Phenols / Q000032:analysis* / Q000652:urine
D000393:Air Pollutants; D000395:Air Pollutants, Occupational; D010578:Petroleum; D010636:Phenols; D001554:Benzene
Analiza metod oceny narazenia zawodowego na benzen i fenol pracowników przemysłu petrochemicznego.