A new graphical rule for rate laws of enzyme reactions with branched pathways.
A new graphical rule is presented for deriving the rate equations of enzyme reactions. The new rule has the following advantages: (i) it is very effective in simplifying the calculations for complex mechanisms, especially for those with branched pathways; (ii) a significant and intuitive correlation between the rule and the mechanism is established through the product-releasing cycle and product-combining cycle.
D055598:Chemical Phenomena; D002621:Chemistry; D004798:Enzymes / Q000378:metabolism*; D007700:Kinetics; D008433:Mathematics; D008954:Models, Biological
D004798:Enzymes