Comparison of three sample preparation techniques for determination of organic bromide and chloride in halogenated lipids by x-ray fluorescence spectroscopy.
Three sample preparation techniques--thin-film, solution, and cellulose pellet--were applied to the determination of bromide in brominated lipids by X-ray fluorescence spectroscopy. Using brominated vegetable oils of known bromide content it was demonstrated that the thin-film technique could result in erroneously high bromide contents, which could also vary with the amount of oil applied, depending on the solvent used. As solutions in hexane, slightly high bromide contents were observed at high concentrations. With the cellulose pellets, bromide contents similar to known values were observed. It was concluded that the cellulose pellet procedure, although more time consuming, and less convenient for ready recovery of sample, was the most suitable for organic bromide determination. Similar results were indicated for chlorinated oils.
D005223:Fats / Q000032:analysis*; D006842:Hydrocarbons, Brominated / Q000032:analysis*; D006843:Hydrocarbons, Chlorinated / Q000032:analysis*; D013052:Spectrometry, X-Ray Emission / Q000379:methods
D005223:Fats; D006842:Hydrocarbons, Brominated; D006843:Hydrocarbons, Chlorinated