Solvent extracts of carbon black--determination of total extractables and analysis for benzo(alpha)pyrene.
The efficiency of three organic solvents for extraction of adsorbates, including polycyclic aromatic hydrocarbons (PAH), on five rubber-grade oil furnace blacks was studied. Measurement of both the percent total extractables and the specific PAH, benzo(alpha)pyrene (B alpha P), showed toluene to be a better extractant than benzene and both to be superior to cyclohexane. Spectral analysis for B alpha P was preceded by chromatographic separation. A thin layer technique was shown to be a rapid and reliable replacement for paper chromatography.
D001580:Benzopyrenes / Q000032:analysis*; D002244:Carbon / Q000032:analysis*; D002854:Chromatography, Paper; D002855:Chromatography, Thin Layer; D012997:Solvents; D013050:Spectrometry, Fluorescence; D013056:Spectrophotometry, Ultraviolet
D001580:Benzopyrenes; D012997:Solvents; D002244:Carbon