title: [Stereochemistry of highly selective transition metal or Lewis acid-catalyzed asymmetric reactions].
abstract: Recent progress of our studies on catalytic asymmetric synthesis is reviewed focused on transition metal-catalyzed intramolecular asymmetric reactions using chiral organo-sulfur groups as main chiral auxiliaries such as asymmetric vinyl-cyclopropane-cyclopentene rearrangements and intramolecular asymmetric metallo-ene reactions, Lewis acid-catalyzed intramolecular asymmetric ene reactions with chiral sulfinyl groups, and palladium-catalyzed intramolecular asymmetric allylations via chiral enamines.
mesh_terms: D000143:Acids; D002384:Catalysis; D003517:Cyclopentanes / Q000737:chemistry; D003521:Cyclopropanes / Q000737:chemistry; D008670:Metals; D008968:Molecular Conformation
chemical_list: D000143:Acids; D003517:Cyclopentanes; D003521:Cyclopropanes; D008670:Metals